Angewandte Chemie International Edition

Abstract :

Frustration leads to overreaction: When diametrically opposed regioselective debenzylation is frustrated, an unexpected double debenzylation reaction affords original tetrafunctionalized cyclodextrins in a controlled and efficient manner. A rationale of the reaction is proposed based on a kinetic study.

Angewandte Chemie International Edition

Um “contra as regras” Double Banco baleado com diisobutilalumínio para permitir funcionalização Triplo de α-Cyclodextrin †

Dr. Elena Zaborova, Maxime Guitet, Dr. Giuseppe Prencipe, Prof. Yves Blériot (IC2MP), Dr. Mickaël Menand, Prof. Matthieu Sollogoub

Artigo publicado on-line: 22 NOV 2012

Palavras Chaves:

– Ciclos côncavos;

– Ciclodextrina;

– Heterofunctionalization;

– Estudos sobre os mecanismos;

– seletividade

Angewandte_Chemie  02

Abstract :

Frustration leads to overreaction: When diametrically opposed regioselective debenzylation is frustrated, an unexpected double debenzylation reaction affords original tetrafunctionalized cyclodextrins in a controlled and efficient manner. A rationale of the reaction is proposed based on a kinetic study.

Angewandte Chemie International Edition

 

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